Sectional gutters come in pre-cut lengths, typically 10 feet, that get joined together with connectors once they're up on the house. Seamless gutters are formed on-site from a single coil of metal, cut to the exact length of each run, with no joints except at corners and end caps.
That difference sounds small, but it shows up in performance. Every seam in a sectional system is a potential leak point, while a seamless run only has to deal with seams at the corners, where leaks are far less common and much easier to seal properly.
The on-site forming process uses a portable rolling machine that a crew brings directly to your home. The machine feeds flat coil stock through a series of rollers that bend it into the finished gutter profile, cut precisely to match each roofline measurement, which is why a seamless install depends on accurate on-site measuring rather than ordering fixed-length stock ahead of time.